Go north on Hwy 25 from London to East Bernstadt. Bear right onto 490 (It's the last light heading north to Rockcastle Co if you are familiar with that area). Go about a mile or two and turn left onto 3094. Cross RR tracks and it is the next right after Litton Town Rd. It's a little white church that sits up on a hill. If you can find the East Bernstadt UMC, it's just in front of that (the UMC is on Litton Town Rd).
OR
Head south on Hwy 25 and look for Carmichael Community Church on the left and take a left onto 3094 beside it. Travel roughly a mile and St Sylvester will be on the left up the hill.